as long as you create a vmkernel portgroup with vmotion enabled on it and has the same name and ip range (same network) or different ip range (network) but if they are tagged on the vswitch so that they can communicate the vmotion will work fine. just make sure on both the hosts you only enalbe vmotion on the vmkernel of the vswitch through which you want the vmotion to occur and u r done.
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